Influence of the Conformation of Methoxy-(2-naphthyl)acetates (2NMA Esters) on Their Chemical Reactions

Shu-ichi FUKUYOSHI; Takashi OOI; Takenori KUSUMI

doi:10.1248/cpb.48.1208

Shu-ichi FUKUYOSHI, Takashi OOI, Takenori KUSUMI

著者情報

キーワード: 2NMA, chiral anisotropic reagent, conformation, steric effect

ジャーナルフリー

2000 年 48 巻 8 号 p. 1208-1210

DOI https://doi.org/10.1248/cpb.48.1208

詳細

抄録

An SN2 reaction (NaI) of 1, 7-di(methanesulfoxyl)heptadien-4-yl methoxy-(2-naphthyl)acetate and a tributyltin hydride reduction of 1, 7-diiodo-4-yl methoxy-(2-naphthyl)acetate (2NMA) is crucial for determination of the absolute configuration of secondary alcohols.

責任著者(Corresponding author)

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