抄録
The infrared spectra of [Cu (glutamate)·(H2O)]n·(H2O)n, [Zn (glutamate)·(H2O)]n·(H2O)n and their isotopic complexes containing metal and hydrogen isotopes have been measured in the region between 4000 and 200 cm-1. The isotope shifts on 63Cu and 65Cu substitution have been observed for bands at 404, 352 and 279 cm-1 of the Cu complex. Bands at 300, 245 and 227 cm-1 of the Zn complex are apparently sensitive to 64Zn and 68Zn substitution. The frequency shifts on N, O-deuteration indicated that a Cu-OOC stretching vibration is localized for the Cu complex whereas Zn-OOC stretching vibrations couple with Zn-NH2 and/or Zn-OH2 stretching vibrations.